Centerville is an unincorporated community and census-designated place in Klickitat County, Washington, United States. Settled in 1877 by Albert J. Brown, the population was 94 at the 2020 census. Centerville is located in south-central Klickitat County 4 miles west of U.S. Route 97, 8 miles southwest of Goldendale, and 11 miles northwest of the Columbia Ri…Centerville is an unincorporated community and census-designated place in Klickitat County, Washington, United States. Settled in 1877 by Albert J. Brown, the population was 94 at the 2020 census. Centerville is located in south-central Klickitat County 4 miles west of U.S. Route 97, 8 miles southwest of Goldendale, and 11 miles northwest of the Columbia River at Maryhill.